Iodine monoxide

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Iodine monoxide
Names
Other names
Iodine(II) oxide, iodosyl, oxidoiodine
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
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1170
  • InChI=1S/IO/c1-2
    Key: AFSVSXMRDKPOEW-UHFFFAOYSA-N
  • [O]I
Properties
IO
Molar mass 142.903 g·mol−1
Appearance purple gas[citation needed]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Iodine monoxide is a binary inorganic compound of iodine and oxygen with the chemical formula IO•. A free radical, this compound is the simplest of many iodine oxides.[1][2][3] It is similar to the oxygen monofluoride, chlorine monoxide and bromine monoxide radicals.

Synthesis

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Iodine monoxide can be obtained by the reaction between iodine and oxygen:[4]

I2 + O2 → 2 IO

Chemical properties

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Iodine monoxide decomposes to its prime elements:[citation needed]

2 IO → I2 + O2

Iodine monoxide reacts with nitric oxide:[5]

2 IO + 2 NO → I2 + 2 NO2

Atmosphere

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Atmospheric iodine atoms (e.g. from iodomethane) can react with ozone to produce the iodine monoxide radical:[6][5]

I2 + 2 O3 → 2 IO + 2 O2

This process can contribute to ozone depletion.[citation needed]

References

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