Tistarite

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Tistarite
General
CategoryOxide minerals
FormulaTi2O3
IMA symbolTta[1]
Strunz classification4.CB.05
Crystal systemTrigonal
Crystal classHexagonal scalenohedral (3m)
H-M symbol: (3 2/m)
Space groupR3c
Identification
References[2]
SEM BSE images showing kaitianite (Ktn) with tistarite (Tta), Ti,Al,Zr-oxide (TAZ), MgTi3+2Al4SiO12 phase (MTAS), spinel (Spl), sapphirine (Spr), and Ti-sulfide (Ti-S) in corundum Grain 1125C2. The upper rectangular area in (b) are enlarged in (c)
SEM BSE images showing kaitianite (Ktn) with tistarite (Tta), Ti,Al,Zr-oxide (TAZ), MgTi3+2Al4SiO12 phase (MTAS), spinel (Spl), sapphirine (Spr), and Ti-sulfide (Ti-S) in corundum Grain 1125C2. The upper rectangular area in (b) are enlarged in (c)[3]

Tistarite is an exceedingly rare mineral with the formula Ti2O3, thus being the natural analogue of titanium(III) oxide.[4][2] In terms of chemistry it is the titanium-analogue of hematite, corundum, eskolaite, and karelianite. Other minerals with the general formula A2O3 are arsenolite, avicennite, claudetite, bismite, bixbyite, kangite, sphaerobismoite, yttriaite-(Y) and valentinite. Tistarite and grossmanite – both found in the famous Allende meteorite (so is kangite) – are the only currently known minerals with trivalent titanium. Titanium in minerals is almost exclusively tetravalent.[2][5][6] The only known terrestrial occurrence of tistarite was found during minerals exploration by Shefa Yamim Ltd. in the upper mantle beneath Mount Carmel, Israel.[3][7]

References

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  1. ^ Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value).
  2. ^ a b c Mindat, Tistarite, http://www.mindat.org/min-38695.html
  3. ^ a b Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value). This article incorporates text from this source, which is available under the CC BY 4.0 license.
  4. ^ Ma, C., and Rossmann, G.R., 2009: Tistarite, Ti2O3, a new refractory mineral from the Allende meteorite. American Mineralogist 94(5–6), 841–844
  5. ^ Mindat, Kangite, http://www.mindat.org/min-42879.html
  6. ^ Mindat, Yttriaite-(Y), http://www.mindat.org/min-40471.html
  7. ^ Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value).