tert-Butyl nitrite
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3D model (JSmol)
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| ECHA InfoCard | Lua error in Module:Wikidata at line 880: attempt to index field 'wikibase' (a nil value). Lua error in Module:Wikidata at line 880: attempt to index field 'wikibase' (a nil value).Lua error in Module:EditAtWikidata at line 29: attempt to index field 'wikibase' (a nil value). | ||
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| E number | Lua error in Module:Wikidata at line 880: attempt to index field 'wikibase' (a nil value). | ||
PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |||
| C4H9NO2 | |||
| Molar mass | 103.121 g·mol−1 | ||
| Appearance | colorless liquid | ||
| Density | 0.867 g/mL | ||
| Boiling point | 61–63 °C (142–145 °F; 334–336 K) | ||
| Hazards | |||
| GHS labelling:[1] | |||
| GHS02: FlammableGHS07: Exclamation mark | |||
| Danger | |||
| H225, H302, H332 | |||
| P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P280, P301+P312, P303+P361+P353, P304+P312, P304+P340, P312, P330, P370+P378, P403+P235, P501 | |||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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tert-Butyl nitrite is an organic compound with the formula (CH3)3CONO. A colorless liquid, it is the tert-butyl ester of nitrous acid and is typically employed as a solution with tert-butyl alcohol.
Use
[edit | edit source]The compound is used as a reagent in organic synthesis.[2] It reacts with secondary amides to give N-nitroso amides:[3]
- RC(O)N(H)R + (CH3)3CONO → RC(O)N(NO)R + (CH3)3COH
See also
[edit | edit source]References
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