Pyrosulfate
In chemistry, disulfate or pyrosulfate is the anion with the molecular formula S
2O2−
7. Disulfate is the IUPAC name. [1]
It has a dichromate-like structure and can be visualised as two corner-sharing SO4 tetrahedra, with a bridging oxygen atom.[2]
In this anion, sulfur has an oxidation state of +6. Disulfate is the conjugate base of the hydrogen disulfate (hydrogen pyrosulfate) ion HS
2O−
7, which in turn is the conjugate base of disulfuric acid (pyrosulfuric acid).
Role in sulfation
[edit | edit source]Industrial production of sulfate ester-based surfactants involves the reaction (sulfation) of fatty alcohols with sulfur trioxide. For example, dodecyl alcohol is sulfated using sulfur trioxide. The reaction proceeds by initial formation of the pyrosulfate:
- 2 SO3 + ROH → ROSO2−O−SO3H
- ROSO2−O−SO3H → ROSO3H + SO3
Several million tons are produced annually.[3]
See also
[edit | edit source]References
[edit | edit source]- ^ International Union of Pure and Applied Chemistry (2005). Nomenclature of Inorganic Chemistry (IUPAC Recommendations 2005). Cambridge (UK): RSC–IUPAC. Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value).. p. 130. Electronic version.
- ^ Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value).
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