Phospholane
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| Names | |
|---|---|
| Preferred IUPAC name
Phospholane[1] | |
| Identifiers | |
3D model (JSmol)
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| 605298 | |
| ChEBI | |
| ChemSpider | |
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| EC Number |
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| E number | Lua error in Module:Wikidata at line 880: attempt to index field 'wikibase' (a nil value). |
| 323930 | |
PubChem CID
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| UNII | |
CompTox Dashboard (EPA)
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| Properties | |
| C4H9P | |
| Molar mass | 88.090 g·mol−1 |
| Appearance | colorless liquid |
| Boiling point | 100–103 °C (212–217 °F; 373–376 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Phospholane is the organophosphorus compound with the formula (CH2)4PH. This colorless liquid is the parent member of a family of five-membered, saturated rings containing phosphorus. Although phospholane itself is only of minor academic interest, the class of C- and P-substituted phospholanes are valued ligands in asymmetric hydrogenation and related areas of homogeneous catalysis.[2] Phospholane is prepared by reduction of 1-chlorophospholane, which in turn is obtained by the reaction of 1-phenylphospholane and phosphorus trichloride.[3]
References
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