Muconolactone Δ-isomerase

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Muconolactone Δ-isomerase
Identifiers
EC no.5.3.3.4
CAS no.37318-46-0
Databases
IntEnzIntEnz view
BRENDABRENDA entry
ExPASyNiceZyme view
KEGGKEGG entry
MetaCycmetabolic pathway
PRIAMprofile
PDB structuresRCSB PDB PDBe PDBsum
Gene OntologyAmiGO / QuickGO
Search
PMCarticles
PubMedarticles
NCBIproteins

In enzymology, a muconolactone Δ-isomerase (EC 5.3.3.4) is an enzyme that catalyzes the chemical reaction

(S)-5-oxo-2,5-dihydrofuran-2-acetate 5-oxo-4,5-dihydrofuran-2-acetate

Hence, this enzyme has one substrate, (S)-5-oxo-2,5-dihydrofuran-2-acetate, and one product, 5-oxo-4,5-dihydrofuran-2-acetate.

This enzyme belongs to the family of isomerases, specifically those intramolecular oxidoreductases transposing C=C bonds. The systematic name of this enzyme class is 5-oxo-4,5-dihydrofuran-2-acetate Delta3-Delta2-isomerase. This enzyme is also called muconolactone isomerase. This enzyme participates in benzoate degradation via hydroxylation.

Structural studies

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As of late 2007, only one structure has been solved for this class of enzymes, with the PDB accession code 1MLI.

References

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