Laricitrin

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Laricitrin
Chemical structure of laricitrin
Chemical structure of laricitrin
Names
IUPAC name
3,3′,4′,5,7-Pentahydroxy-5′-methoxyflavone
Systematic IUPAC name
2-(3,4-Dihydroxy-5-methoxyphenyl)-3,5,7-trihydroxy-4H-1-benzopyran-4-one
Other names
3'-O-Methylmyricetin
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
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KEGG
UNII
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  • InChI=1S/C16H12O8/c1-23-11-3-6(2-9(19)13(11)20)16-15(22)14(21)12-8(18)4-7(17)5-10(12)24-16/h2-5,17-20,22H,1H3 ☒N
    Key: CFYMYCCYMJIYAB-UHFFFAOYSA-N ☒N
  • InChI=1/C16H12O8/c1-23-11-3-6(2-9(19)13(11)20)16-15(22)14(21)12-8(18)4-7(17)5-10(12)24-16/h2-5,17-20,22H,1H3
    Key: CFYMYCCYMJIYAB-UHFFFAOYAK
  • O=C1c3c(O/C(=C1/O)c2cc(O)c(O)c(OC)c2)cc(O)cc3O
Properties
C16H12O8
Molar mass 332.264 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Laricitrin is an O-methylated flavonol, a type of flavonoid. It is found in red grape (absent in white grape)[1] and in Vaccinium uliginosum (bog bilberries).[2] It is one of the phenolic compounds present in wine.[3]

Metabolism

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Laricitrin is formed from myricetin by the action of the enzyme myricetin O-methyltransferase.[4] It is further methylated by laricitrin 5'-O-methyltransferase into syringetin.

Glycosides

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References

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  4. ^ Syringetin biosynthesis pathway on metacyc.org
  5. ^ Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value).
  6. ^ Flavonoids isolated from Medicago littoralis Rhode (Fabaceae): their ecological and chemosystematic significance Archived 2011-07-22 at the Wayback Machine