Inherent viscosity

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In polymer science, inherent viscosity is the ratio of the natural logarithm of the relative viscosity of a polymer to its mass concentration.[1] Inherent viscosity scales inversely to mass density, and a common unit is dL/g.

Inherent viscosity is defined as [2] ηinh=lnηrelc where c is the mass concentration of the polymer and ηrel is the relative viscosity, which is defined as ηrel=ηηs where η is the viscosity of the solution and ηs is the viscosity of the solvent.

The definition of ηinh is a finite difference approximation to the derivative d(ln(η))dc|c=0 That ideal limiting value is the intrinsic viscosity,[3][4] which is a good measure of the polymerization degree.[5][6]

References

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  1. ^ Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value).
  2. ^ Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value).
  3. ^ Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value).
  4. ^ Osuji 2009, §1.3: Intrinsic viscosity determination.
  5. ^ Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value). Note that there are several typos in Osuji's displays, including an extra "c" in equation (7; §1.3); and a missing logarithm in the initial definition of inherent viscosity (§1.1).
  6. ^ Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value).