Dimethoxytrityl

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Dimethoxytrityl
Names
IUPAC name
bis(4-methoxyphenyl)-phenylmethyl radical
Other names
  • 4,4'-Benzylidenedianisole
  • 4,4'-Dimethoxytrityl cation
  • 4,4'-Dimethoxytriphenylmethyl radical
  • Bis(p-methoxyphenyl)phenylmethyl radical
  • DMT
Identifiers
3D model (JSmol)
ChemSpider
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EC Number
  • -H: 231-356-7
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UNII
  • -H: {{#property:P3117}}Lua error in Module:EditAtWikidata at line 29: attempt to index field 'wikibase' (a nil value).
  • -H: InChI=1S/C21H20O2/c1-22-19-12-8-17(9-13-19)21(16-6-4-3-5-7-16)18-10-14-20(23-2)15-11-18/h3-15,21H,1-2H3
    Key: RIRAVPPUGSNYOU-UHFFFAOYSA-N
  • +: InChI=1S/C21H19O2/c1-22-19-12-8-17(9-13-19)21(16-6-4-3-5-7-16)18-10-14-20(23-2)15-11-18/h3-15H,1-2H3/q+1
    Key: JLRBVXBVFZQEHA-UHFFFAOYSA-N
  • -H: COC1=CC=C(C=C1)C(C2=CC=CC=C2)C3=CC=C(C=C3)OC
  • +: COC1=CC=C(C=C1)C(=C2C=CC(=[O+]C)C=C2)C3=CC=CC=C3
Properties
C21H19O2
Molar mass 303.4
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Dimethoxytrityl, often abbreviated DMT, is a protecting group widely used for protection of the 5'-hydroxy group in nucleosides, particularly in oligonucleotide synthesis.[1]

It is usually bound to a molecule, but can exist as a stable cation in solution, where it appears bright orange.[2]

References

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