Armstrong process

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The Armstrong process is used to refine titanium. Its output is particle-sized dust which can be sprayed into pattern-molds.[1][2][3] It was patented in 1999.[4] The output of this process has a "coral-like morphology", which differs from the traditional outputs like "spherical gas-atomized powder, mechanically crushed angular particles, or the titanium sponge morphology created during the Kroll process."[3]

History

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The Armstrong process was patented in 1999.[4]

In 2016 a paper by MacDonald et al. told that the Armstrong powder was produced directly from the reduction of Titanium tetrachloride "in a continuous liquid loop", and cost only "11-24 USD/kg",[3] or roughly an order of magnitude higher than the price of steel.[5]

Description

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The reducing agent for the Armstrong process is sodium, which is liquefied and introduced in a combined stream with titanium tetrachloride.[4]

TiCl4+4Na98ACTi+4NaCl

References

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  1. ^ Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value).
  2. ^ W.H.P. Bill, C.A. Blue, J.O. Kiggans, and J.D.K. Rivard, Powder Metallurgy and Solid State Processing of Armstrong Titanium and Titanium Alloy Powders, ITA Annual Conference 2007
  3. ^ a b c Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value).
  4. ^ a b c U.S. patent 5,958,106
  5. ^ Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value).