Triethylsilane
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| Names | |
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| Preferred IUPAC name
Triethylsilane | |
| Identifiers | |
3D model (JSmol)
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| E number | Lua error in Module:Wikidata at line 880: attempt to index field 'wikibase' (a nil value). |
PubChem CID
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| UNII | |
CompTox Dashboard (EPA)
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| Properties | |
| C6H16Si | |
| Molar mass | 116.28 g/mol |
| Appearance | colorless liquid |
| Density | 0.728 g/mL |
| Melting point | −156.1 °C (−249.0 °F; 117.0 K) |
| Boiling point | 107–108 °C (225–226 °F; 380–381 K) |
| log P | 3.08 |
| Vapor pressure | 31 hPa at 20 °C 75 hPa at 38 °C 126 hPa at 50 °C |
| Hazards | |
| GHS labelling: | |
| GHS02: Flammable | |
| Danger | |
| H225, H412[1] | |
| P210, P273[1] | |
| Flash point | −2.99 °C (26.62 °F; 270.16 K) closed cup[1] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Triethylsilane is the organosilicon compound with the formula (C2H5)3SiH. It is a trialkylsilane. The Si-H bond is reactive.
It was first discovered by Albert Ladenburg in 1872 among the products of reduction of tetraethyl orthosilicate with sodium and diethylzinc.[2] He also prepared it by a stepwise reduction via ethoxytriethylsilane and named it silicoheptyl hydride, reflecting the idea of a silicon compound analogous to a seven-carbon hydrocarbon.
This colorless liquid is used in organic synthesis as a reducing agent and as a precursor to silyl ethers.[3] As one of the simplest trialkylsilanes that is a liquid at room temperature, triethylsilane is often used in studies of hydrosilylation catalysis.[4]
Additional reading
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References
[edit | edit source]- ^ a b c Sigma-Aldrich Co., Triethylsilane. Retrieved on 2015-01-30.
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