Octachlorodibenzodioxin

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Octachlorodibenzodioxin
Skeletal formula
Skeletal formula
Ball-and-stick model
Ball-and-stick model
Names
Preferred IUPAC name
Octachlorooxanthrene
Other names
OCDD, Octachlorodibenzo-p-dioxin
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
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EC Number
  • 694-813-3
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KEGG
UNII
UN number 2811 (OCTACHLORODIBENZO-P-DIOXIN)
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  • InChI=1S/C12Cl8O2/c13-1-2(14)6(18)10-9(5(1)17)21-11-7(19)3(15)4(16)8(20)12(11)22-10
    Key: FOIBFBMSLDGNHL-UHFFFAOYSA-N
  • ClC1=C2C(OC(C(Cl)=C(Cl)C(Cl)=C3Cl)=C3O2)=C(Cl)C(Cl)=C1Cl
Properties
C12Cl8O2
Molar mass 459.73 g·mol−1
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
liver damage, chloracne
GHS labelling:[1]
GHS06: ToxicGHS09: Environmental hazard
Danger
H300, H410
P264, P270, P273, P301+P316, P321, P330, P391, P405, P501
Related compounds
Tetrachlorodibenzodioxin
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Octachlorodibenzodioxin (abbreviated as OCDD or OctaCDD) is one of polychlorinated dibenzodioxins (PCDDs). When compared to 2,3,7,8-tetrachlorodibenzodioxin (TCDD), its toxicity is about 3000 times weaker.[1]

It is one of the dominant PCDD congeners in smoke emissions, but because it is much less soluble than TCDD, it is not bioaccumulated as effectively and it is toxicologically less important than the most prevalent dioxins. (For details see Dioxins and dioxin-like compounds).

Chlorinated pesticides can also contain impurities of polychlorinated dibenzodioxins and polychlorinated dibenzofurans (PCDD/Fs) and their precursors. "Precursor formation of PCDD/Fs can also be mediated by ultraviolet light (UV)" from sun (OCDD mostly). Changes in congeners ratio after UV exposition suggest that pesticide sources of dioxines-like after sunlight exposure "may not be recognized based on matching source fingerprints established from manufacturing impurities. These changes also provide preliminary insights into the possible formation routes and types of precursors involved".[2]

References

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