3-Nitrotoluene
(Redirected from Meta-nitrotoluene)
| Names | |
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| Preferred IUPAC name
1-Methyl-3-nitrobenzene | |
| Other names
m-Nitrotoluene
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| Identifiers | |
3D model (JSmol)
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PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| C7H7NO2 | |
| Molar mass | 137.138 g·mol−1 |
| Appearance | yellow liquid[1] |
| Odor | mild, aromatic[1] |
| Density | 1.1581 g·cm−3 @ 20°C [2] |
| Melting point | 15.5 °C (59.9 °F; 288.6 K)[2] |
| Boiling point | 232 °C (450 °F; 505 K)[2] |
| 0.05% (20°C)[1] | |
| Vapor pressure | 0.1 mmHg (20°C)[1] |
| −72.71·10−6 cm3/mol | |
| Hazards | |
| Flash point | 106 °C; 223 °F; 379 K[1] |
| Explosive limits | 1.6%-?[1] |
| NIOSH (US health exposure limits): | |
PEL (Permissible)
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TWA 5 ppm (30 mg/m3) [skin][1] |
REL (Recommended)
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TWA 2 ppm (11 mg/m3) [skin][1] |
IDLH (Immediate danger)
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200 ppm[1] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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3-Nitrotoluene or meta-nitrotoluene is an organic compound with the formula CH3C6H4NO2. It is one of three isomers of nitrotoluene. A yellow liquid, it is used in the manufacture of meta-toluidine, which is an intermediate in the production of various dyes.[3]
Synthesis and reactions
[edit | edit source]It is made by nitrating toluene by conventional mixed acid (acetyl nitrate doesn't produce it[4]): this reaction mainly affords a 2:1 mixture of 2-nitro and 4-nitro isomers, but after removal of the 2-isomer, the 3-nitrotoluene can be purified by distillation. It is a precursor to toluidine, which is used in producing azo dyes.[3]
References
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