Lithium borate

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Lithium tetraborate
File:EntryWithCollCode419669.png
Names
Other names
Lithium borate
Identifiers
3D model (JSmol)
ChemSpider
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EC Number
  • 234-514-3
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UNII
  • {{#property:P3117}}Lua error in Module:EditAtWikidata at line 29: attempt to index field 'wikibase' (a nil value).
  • InChI=1S/B4O7.2Li/c5-1-9-3(7)11-4(8)10-2-6;;/q-2;2*+1 checkY
    Key: PSHMSSXLYVAENJ-UHFFFAOYSA-N checkY
  • InChI=1/B4O7.2Li/c5-1-9-3(7)11-4(8)10-2-6;;/q-2;2*+1
    Key: PSHMSSXLYVAENJ-UHFFFAOYAA
  • [Li+].[Li+].O=BOB([O-])OB([O-])OB=O
Properties
Li2B4O7
Molar mass 169.11 g/mol
Appearance white powder
Density 2.4 g/cm3, solid
Melting point 917 °C (1,683 °F; 1,190 K)
moderately soluble
Hazards
NFPA 704 (fire diamond)

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2
0
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Safety data sheet (SDS) External MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Lithium borate,[1] also known as lithium tetraborate,[2] dilithium tetraborate[3] or boron lithium oxide[2] is an inorganic compound with the formula Li2B4O7. A colorless solid, lithium borate is used in making glasses and ceramics. It is not to be confused with B8Li2O13, also called lithium borate.[4]

Structure

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Its structure consists of a polymeric borate backbone. The Li+ centers are bound to four and five oxygen ligands. Boron centers are trigonal and tetrahedral.[5][6]

File:65930-ICSD.png
Borate backbone of Li2B4O7.

Lithium borate can be used in the laboratory as LB buffer for gel electrophoresis of DNA and RNA. It is also used in the borax fusion method to vitrify mineral powder specimens for analysis by WDXRF spectroscopy.[7]

See also

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References

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  1. ^ Lithium borate
  2. ^ a b Boron lithium oxide
  3. ^ dilithium tetraborate
  4. ^ Lithium borate
  5. ^ Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value).
  6. ^ Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value).
  7. ^ Ron Jenkins, X-Ray Fluorescence Spectrometry, Second Edition, J. Wiley & Sons Inc., 1999, Lua error in Module:Citation/CS1/Configuration at line 2172: attempt to index field '?' (a nil value)., p 146-7.